Zanini istituto di chimicafisica, elettrochimica e metallurgia del politecnlco di milano, centro di studio del cnr sui processi elettrodici, piazza leonardo da vinci 32, 203 milano, italy. Effects of marine environments on stress corrosion cracking of austenitic stainless steels 1011820 effective december 6, 2006, this report has been made publicly available in accordance with section 734. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution. A phenomenon that regularly plagues the standard austenitic stainless steels of type aisi 304316 is stress corrosion cracking scc. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. The effect of salt loading on chlorideinduced stress. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. Chloride stress corrosion cracking inspectioneering. Stress corrosion cracking scc is one failure mode that may occurred on hot insulated austenitic stainless steel pressure vessels and piping.
Preventing stress corrosion cracking of austenitic stainless steels in chemical plants by masao nakahara. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. This report summarizes work performed at argonne national laboratory on irradiationassisted stress corrosion cracking iascc of austenitic stainless steels that were irradiated in the halden reactor in simulation of irradiationinduced degradation of boiling water reactor bwr core internal components. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. The phenomenon of transgranular stress corrosion cracking of austenitic stainless steels in aqueous chloride environments has been recognized. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e.
The austenitic stainless steel series 300 is more susceptible in an environment containing chlorides. Corrosion of unprotected carbon steel occurs even inside reinforced. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. Stress corrosion cracking of austenitic stainless steel. The oxide originated on surface could act as a crack initiator and a crack propagation would progress along grain boundaries and particularly along tunnel of pores. In both steels the coldworked material cw showed higher crack propagation rate than annealed one st, where the variation of the propagated crystal planes of. A general definition of the phenomenon is that scc is the fracture of a material by the simultaneous action of a tensile stress and a corrosive environment. Irradiationinduced stress corrosion cracking of austenitic. Carbon steel and ferritic stainless steels, with little to no nickel, do not experience cl scc, nor do high nickel alloys those with ni over 30% are much less prone. In 2007, badak lng experienced this problem on its amine regenerator pressure vessel where the shell are insulated and made of austenitic stainless steel grade 304l. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking scc of type. In aqueous chloride environments austenitic stainless steels and many nickel based alloys are common to perform poorly.
In essence, on their own, ferritic stainless steel and austenitic stainless steel dont handle stress corrosion cracking admirably. This paper discusses various cases of scc and stress induced cracking sic that normally occur with austenitic stainless steel in fertilizer plants and describes three case studies. Effect of ph and chloride contents on stress corrosion cracking of austenitic stainless steels at room temperature h. The most susceptible austenitic grades have nickel contents in the. Stress corrosion cracking is a general term describing stressed alloy failures appearing as cracks in the stainless steel that occur in corrosive environments. Ahmed and others published stress corrosion cracking of austenitic stainless steels in chloride environment find. The scc propensity of austenitic stainless steels in marine environments is affected by many variables including the amount of moisture and time of wetness, airborne contaminants e. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. Chloride stress corrosion cracking cscc is a type of intergranular corrosion.
Stress corrosion cracking scc of duplex stainless steel. In austenitic stainless steel, the main forms of corrosion are pitting and stress corrosion cracking caused by chlorides. Stress corrosion cracking in duplex stainless steel. They can be subject to polythionic acid stress corrosion cracking during shut down. Stress corrosion cracking of austenitic stainless steels 687 in view of the ambiguity in the various mechanisms for explaining scc in austenitic stainless steels, an attempt has been made to understand further the mechanism by combining fracture mechanics, acoustic emission, metallurgical and. Fracture path of stress corrosion cracks in austenitic. Abstract the drip procedure from the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress. The methodology of the drip procedure of the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as applies to the insulation industry. Stress corrosion cracking is the failure of austenitic stainless steels caused by the combined action of a corrosive atmosphere and residual stress in the metal. Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern.
On the stress corrosion cracking mechanisms of austenitic. In order to understand the stress corrosion cracking behavior of metastable and stable austenitic stainless steels, constant elongation rate tests cert and subcritical crack growth scg tests were used to measure the susceptibility and cracking rate. The effect of cold work on the stresscorrosion cracking of. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. Prevention of external chloride stress corrosion cracking of.
Austenitic grades, however, are susceptible to chloride stress corrosion cracking scc and are not recommended for service that combines tensile stress and the presence of chlorides, even at moderate temperatures. Of course, the conditions under which these metals exist will also have a lot to do with whether or not stress corrosion cracking occurs. Effect of halogens and inhibitors on the external stress. The properties of austenitic stainless steels ass such as corrosion resistance, manufacturability, ductility, abundant industrial experience, and low cost, make ass a favourable alloy choice for many industries. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Experimental data from published literature on stress corrosion cracking scc of austenitic stainless steels ss as influenced by temperature and stress in concentrated chloride solutions were analyzed using the chemicalmechanical correlation model. Corrosion of this type has been extensively studied and affects almost all metal alloys, including the austenitic grades of stainless steel used in brewing. Chlorideinduced stress corrosion cracking ciscc in the weldments of austenitic stainless steel canisters is one of the primary safety concerns duri. The following sandvik grades have very good or excellent resistance to chlorideinduced stress corrosion cracking. Duplex stainless steels have roughly twice the yield strength of austenitic stainless steel. Nureger7030, atmospheric stress corrosion cracking susceptibility of welded and unwelded 304, 304l, and 316l austenitic stainless steels commonly used for dry storage containers exposed to marine environments, usnrc, october 2010.
The ferritic steels are more resistant to localized corrosion than are the austenitic steels, which is responsible for the difference in the influence of prior thermal and mechanical history on cracking susceptibility of the two types of steel. In this study the influence of operating conditions such as chloride concentration, temperature on stress corrosion cracking of austenitic stainless steel will be investigated. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Review of recent studies on the mechanism of stress. Chloride stress corrosion cracking in austenitic stainless steel. Stress corrosion cracking scc of austenitic stainless and. The nickel content in austenitic stainless steels helps to reduce the rate of corrosion, particularly in acid environments. The stress corrosion cracking of austenitic stainless steel heat exchange tubes. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. Their morphology and crystal orientation were analyzed. Modelling hydrogen induced stress corrosion cracking in.
Report 1011820, effects of marine environments on stress corrosion cracking of austenitic stainless. This diagram figure 1 is analogous to a similar diagram for caustic. Grades with high resistance to chlorideinduced stress corrosion cracking scc duplex stainless steels, austenitic stainless steels with a high nickel content 25%. Intergranular stress corrosion cracking was observed. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
Pitting and stress corrosion cracking behavior of austenitic stainless steel weldments containing retained ferrite. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Effect of ph and chloride contents on stress corrosion. Stress corrosion cracking of duplex stainless steels. The stress corrosion cracking of austenitic stainless. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Effects of marine environments on stress corrosion.
Integral to johns manville thermo1200 and to sproule wr1200 is xox corrosion inhibitor, a distinctive formula and process that inhibits corrosion to the outside surfaces of pipe and equipment, especially stress corrosion cracking of austenitic stainless steel. Their mixed microstructure provides improved resistance to chloride stress corrosion cracking in comparison to austenitic stainless steel types 304 and 316. Irradiationinduced stress corrosion cracking of austenitic stainless steels. Chlorides will not cause scc unless an aqueous phase is present. The major emphasis is placed on the cracking which occurs in chloride environments, although other environments are mentioned. Ferritic steels are also resistant to cracking but may corrode. Effects of stress and temperature on stress corrosion. Overstressed ubends of types 304 and 347 stainless steels were exposed to water containing chloride ions to determine the susceptibility of these steels to stress corrosion cracking between the temperatures of 165 f and 200 f. Chlorideoxygen stress corrosion cracking mechanisms of austenitic chromiumnickel steels in high purity water at 250 to 350 c over a wide range of stress levels is reported.
Stress corrosion cracking of austenitic stainless steels. Behaviour of stress corrosion cracking of austenitic stainless. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Why are austenitic stainless steels more susceptible to. Stress corrosion cracking in duplex stainless steel great. Stress corrosion cracking of an austenitic stainless steel in nitritecontaining chloride solutions r.
Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure. On residual stress analysis and microstructural evolution. Stress corrosion cracking on an insulated austenitic. Quasicleavage facets have been detected in the stress corrosion cracking fracture of type 304 and type 316 austenitic stainless steels under an environment containing chloride. Type 304 is extensively used in such items as, cookware, cutlery, and kitchen equipment. The general pattern of the observed failures indicates that as nuclear plants age and fluence increases, various apparently nonsensitized austenitic stainless steels. A phenomenon that regularly plagues the standard austenitic stainless steels of type aisi 304316 is stresscorrosion cracking scc.
Feb 28, 2018 however, ferritic steel is still fairly vulnerable to stress corrosion cracking. Stress corrosion cracking of stainless steels springerlink. Duplex stainless steels, austenitic stainless steels with a high nickel content 25 %. Stress corrosion cracking scc of austenitic stainless steel weld metal. Chloride stress corrosion cracking of austenitic stainless. Duplex stainless steels, austenitic stainless steels with a high nickel content 25%. Stress corrosion cracking facts and how to reduce the risk. Effect of plastic deformation induced by cold rolling or surface machining on the susceptibility to chlorideinduced stress corrosion cracking at ambient temperature of 304l austenitic stainless. Stress corrosion cracking scc of austenitic stainless. Chloride induced stress corrosion cracking of stainless steel. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Austenitic stainless steels are widely used in hydroprocessing units.
In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev. The benefits of n to scc resistance of dss are provided. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Chloride induced stress corrosion cracking of stainless. Juang 1 chung shan institute of science and technology, box 9000883, lungtan, taiwan, roc. Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl. This paper presents a fusion welding process that was developed for snf canister repair. Chloride stress corrosion cracking of an austenitic. Pdf stress corrosion cracking of austenitic stainless steels in. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride. This paper discusses various cases of scc and stress induced cracking sic that normally occur with austenitic stainless steel in. Stress corrosion cracking scc is a common issue with many specialty alloys.
Caustic stress corrosion cracking inspectioneering. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and. Singh raman 1, and wai hoong siew 2 1 department of mechanical and aerospace engineering, monash university, melbourne, victoria 3800, australia 2 mechanical engineer, ibm australia 60 city road melbourne, victoria 3006 australia. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. All different metals can experience stress corrosion cracking, but some of them experience it much easier than others. A model has been developed which simulates the deformation of single crystal austenitic stainless steels and captures the effects of hydrogen on stress corrosion cracking.
Exposure of the austenitic stainless steel piping or equipment to moisture and air can lead to a potential for this type of cracking if the ss is sensitized. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Type 316 is the next most common austenitic stainless steel. Sensor requirements for detection and characterization of. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions. Intergranular stress corrosion cracking of welded steel twi. Addition of nitrite to the chloride solution, which is reported to have inhibitive influence on corrosion of stainless. Stress corrosion cracking of an austenitic stainless steel in. The potential for stress corrosion cracking scc of welded stainless steel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap.
Oct 08, 20 thermowells can breathe in atmospheric moisture. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment it is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. Certain austenitic stainless steels and aluminium alloys crack in the presence of chlorides. On the stress corrosion cracking and hydrogen embrittlement. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test. For this reason, they cant be used to serve a number of different functions. It appears that stress corrosion cracking in austenitic stainless steels in the presence of chlorides proceeds transgranularly and usually occurs at temperature above 70c 39, 40. Irradiationinduced stress corrosion cracking of austenitic stainless steel s. Crystal orientation analysis on stress corrosion cracking. The effect of cold work on stress corrosion cracking of type 302 austenitic stainless steel wire exposed to boiling 154 c, 309 f 42 weightpercent aqueous magnesium chloride solution was determined. Both of type 304 and type 316 stainless steels showed quite similar. Chloride stress corrosion cracking in austenitic stainless.
Induced stress corrosion cracking of austenitic stainless. Proceedings of the asme 2010 pressure vessels and piping divisionkpvp conference. Effects of fluoride and other halogen ions on the external. This limits the usefulness of austenitic stainless steel for containing. The most common austenitic stainless steel and most common of all stainless steel is type 304, also known as 188 or a2. However, ass can fail if conditions exist that lead to stress corrosion cracking scc 1, 2.
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